Jiexiang Ouyang, Yan Xu, L. Khoo
Jun 30, 1998
Citations
1
Influential Citations
15
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The reactions of 8-methoxyquinoline (C10H9ON) with R2SnCl2 (R=Ph, Me, n-Bu) have been investigated. All these reactions yielded the corresponding distannoxanes, [(R2SnCl)2O]2, 8-methoxyquinolinium chloride for R=n-Bu and organostannate salts for R=Ph, Me. The central tin atom of the stannate salts is not bonded to the two N and O donor atoms of the ligand species. X-ray structural analysis was performed on the complexes, [C10H9ON·H·NOH9C10]Ph2SnCl3 and [C10H9ON·H]2Ph2SnCl4 , and the results along with those obtained from a variety of physical measurements for these products are discussed. In addition, it was found that the Ph2SnCl3− moiety present in [C10H9ON·H·NOH9C10]Ph2SnCl3 disproportionated into Ph2SnCl2 and Ph2SnCl42−.