R. C. Cambie, C. M. Read, P. Rutledge
Feb 17, 1981
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0
Influential Citations
1
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Journal
Journal of The Chemical Society-perkin Transactions 1
Abstract
The reaction of androsta-3,5-diene and of androsta-3,5-dien-17-one with one or 2 molar equiv. of m-chloroperbenzoic acid give complex mixtures of products. Only low yields of diepoxides are formed using 2 equiv. of peracid in ether as solvent, unsaturated vic-3,4-diols being the major products. Use of 1 equiv. of peracid leads, inter alia, to unsaturated hydroxy-m-chlorobenzoates. The formation of these and other products are discussed.