H. Ang, W. Lien
1977
Citations
0
Influential Citations
8
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract Tris(pentafluorophenyl)phosphine is oxidised by bis(trifluoromethyl)nitroxyl to form tris(pentafluorophenyl)phosphine oxide and perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane). With the corresponding arsine and stibine, addition products are obtained, namely tris(pentafluorophenyl)-arsenicdi[bis(trifluoromethyl)nitroxide] and tris(pentafluorophenyl)-antimonydi[bis(trifluoromethyl)nitroxide] respectively. Some reactions of the new derivatives are described.