W. P. Fehlhammer, K. Bartel, R. Metzner
Jun 1, 2008
Citations
0
Influential Citations
5
Citations
Journal
Zeitschrift für anorganische und allgemeine Chemie
Abstract
The isocyanide complexes (R = CH2CO2Et, CH2Ph, C6H11, CH2SO2C6H4-p-Me) react with hexafluoroacetone-sesquihydrate, (F3C)2CO·1,5 H2O, in the presence of triethylamine to give the carboxamido (carbamoyl) complexes [Pt(Cl){C(=O)NHR}(PPh3)2]. Under the same conditions the isocyanoamine complexes trans- are transformed into the isocyanato complex trans-[Pt(Cl)(NCO)(PPh3)2].