K. Itoh, Nobu Kato, Y. Ishii
Mar 1, 1970
Citations
0
Influential Citations
32
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The reactions between (trimethylsilyl)amines or heptamethyldisilazane and p-substituted benzenesulfonyl isocyanates occurred exothermically at room temperature, giving 1 1 adducts quantitatively. Pyrolysis of the adducts of heptamethyldisilazane with arenesulfonyl isocyanates afforded N,N-bis(trimethylsilyl)arenesulfonamides and methyl isocyanate. This result was quite different from that found in our former pyrolyses of isocyanate adducts.