S. Bartlett, R. Chambers, A. Lindley
Sep 30, 1980
Citations
0
Influential Citations
7
Citations
Journal
Journal of The Chemical Society-perkin Transactions 1
Abstract
Reaction of perfluoro-3,4-dimethylhex-3-ene (1) with amine gives products which arise from nucleophilic attack directly on (1) but also products derived from attack on isomers of (1), i.e. perfluoro-3,4-dimethylhex-2-ene (2) and perfluoro-3-methylene-4-methylhexane (3), promoted by fluoride ion which is generated during reaction. The products obtained depend critically on the steric requirements of the attacking amine, e.g. Et2NH gives products arising exclusively from attack on isomer (3).