M. Tordeux, C. Wakselman
Aug 1, 1985
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Journal
Journal of Fluorine Chemistry
Abstract
Abstract Condensation of 1,1,2-trichlorotrifluoroethane with potassium thiophenoxide occurs in DMF or DMSO to give aryl-2,2- dichloro-1,1,2-trifluoroethylsulfides: The same condensation with phenoxide gives two products: The formation of aryl-2,2-dichloro-1,1,2-trifluoroethylsulfides or ethers can be explained by a chain carbanionic mechanism.