M. Tamm, F. Hahn
Feb 1, 1999
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Coordination Chemistry Reviews
Abstract
Abstract Aspects of the coordination chemistry of β-functional phenyl isocyanides are reviewed, with emphasis on research involving 2-hydroxyphenyl isocyanide and derivatives thereof, which has been carried out in our Berlin group during the last few years. The driving force of coordinated 2-hydroxyphenyl isocyanide to form carbene complexes with 2,3-dihydrobenzoxazol-2-ylidene ligands depends on the attached metal fragment and can be used as a probe for the π-electron release ability of the metal center. Related work on N- and C-functional phenyl isocyanides aimed towards the synthesis of 2,3-dihydro-1H-imidazol-2-ylidene and 2,3-dihydro-1H-indol-2-ylidene complexes is also described.