Masahiro Fukuda, Yoshiki Okamoto, Hiroshi Sakurai
1977
Citations
0
Influential Citations
4
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Chloroacetanilide and p-methylchloroacetanilide reacted with phosphoryl chloride to give 2-chloromethyl-3-chloro-4-anilinoquinoline and 2-chloromethyl-3-chloro-4-(p-toluidino)-6-methylquinoline respectively. In the case of propionanilide, 2-ethyl-3-methyl-4-anilinoquinoline was obtained when the reaction was carried out at 20–30 °C. On the other hand, when the reaction temperature was raised to 80–100 °C, N-(1-chloro-1-propenyl)-N,N′-diphenylacetamidine was obtained.