P. Jutzi, Ullrich Gilge
Mar 22, 1983
Citations
0
Influential Citations
1
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Reaction of benzthiazol-2-yl and benzoxazol-2-yl-trimethylstannane with methyltrichlorogermane leads to the mono-, bis- and tris-heterocyclic substituted germanes RGe(Me)Cl 2 , R 2 Ge(Me)Cl, R 3 GeMe ( 2 , 3 , 4 : R = benzthiazol-2-yl; 6 , 7 , 8 : R = benzoxazol-2-yl), which exist in a mobile equilibrium. From the chlorogermanes 2 , 3 and 6 , 7 the corresponding germanes 9 , 10 and 11 , 12 can be obtained by reaction with trimethylstannane. From the germane 10 the mono- and bis- N -methylated salts 15 and 17 can be synthesized. The compounds 10 , 12 and 15 easily decompose by α-elimination reactions. The salt 17 can be regarded as a suitable model substance for the synthesis of a germacyanine dye.