Yong-Kook Choi, B. Kim, Su-Moon Park
1993
Citations
0
Influential Citations
18
Citations
Journal
Journal of The Electrochemical Society
Abstract
Electrochemical reduction of thionyl chloride has been studied at a molybdenum electrode employing cyclic voltammetric, chronocoulometric, and chronoamperometric techniques. The charge transfer process is affected strongly by the film formed on the electrode surface during the reduction. The exchange rate constants, k 0 , of the order of 10 -6 cm/s were observed at fresh electrodes, whereas much smaller constants of about 10 -10 cm/s were observed at film-covered electrodes