J. Faller, N. Sarantopoulos
Mar 30, 2004
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0
Influential Citations
32
Citations
Journal
Organometallics
Abstract
The results of a systematic variation of achiral monodentate ligands used for the Pd-catalyzed alkylation of crotyl and 3-buten-2-yl acetates and carbonates are presented. A significant degree of retention of regiochemistry and stereochemistry was observed for these substrates, especially for nonracemic 3-buten-2-yl ethyl carbonate with PCyxPh3-x and carbene ligands.