Brendan T. Parr, Samantha A. Green, H. Davies
Mar 14, 2013
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Journal
Journal of the American Chemical Society
Abstract
The synthesis of highly functionalized pyrroles has been achieved by reaction of rhodium-stabilized imino-carbenes with furans. The reaction features an initial [3+2] annulation to form bicyclic hemiaminals, followed by ring opening to generate trisubstituted pyrroles.