Noriaki Fujita, Ken Motokura, K. Mori
Jul 17, 2006
Citations
0
Influential Citations
18
Citations
Journal
Tetrahedron Letters
Abstract
Treatment of a hydrotalcite with an aqueous solution of rhodium trichloride results in a Rh-grafted hydrotalcite (Rh/HT) with monomeric Rh species on the surface, which successfully promoted 1,4-addition of organoboron reagents to α,β-unsaturated carbonyl compounds. Furthermore, this catalyst was reusable and was found to be applicable to a one-pot synthesis of 3,3-diarylnitrile.