Yu Tian, Yuanhao Wang, Hai Shang
Jan 14, 2015
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0
Influential Citations
34
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Journal
Organic & biomolecular chemistry
Abstract
Rhodium(II)-catalyzed intramolecular [4 + 3] cycloadditions of dienyltriazoles have been developed, which enable the efficient synthesis of various fused 2,5-dihydroazepines. Mechanistically, the titled reaction proceeds via an interesting tandem cyclopropanation/aza-cope rearrangement.