C. Addicott, P. Bernhardt, C. Wentrup
Jan 4, 2009
Citations
0
Influential Citations
5
Citations
Journal
Arkivoc
Abstract
8-Cyanotetrazolo[1,5-a]pyridine 6T undergoes photochemical ring expansion to afford 1,3-diazepine 7 with diisopropylamine, but with stronger nucleophiles such as dimethylamine a rapid, quantitative ring opening reaction affords dienyltetrazoles 8 and 9 in the dark ( an Addition of Nucleophile - Ring Opening reaction).