F. B. Wampler, R. R. Kuntz
Mar 1, 1971
Citations
0
Influential Citations
6
Citations
Journal
International Journal of Chemical Kinetics
Abstract
The rate constant for the combination of 1,1-dichloro-2,2,2-trifluoroethyl radicals in the gas phase has been measured by applying the rotating sector technique to the 1,1,1-trichloro-2,2,2-trifluoroethane–cyclohexane photochemical system. The combination rate constant, k5, was found to be 6.6 × 1012 cc mole−1 sec−1. Arrhenius parameters for the reaction, are given by the expression log k4 = 11.81 – (9700/2.3RT).