A. Albinati, Qiongzhong Jiang, H. Rüegger
Oct 1, 1993
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0
Influential Citations
26
Citations
Journal
Inorganic Chemistry
Abstract
A compound of composition «RuCl 2 (ETP)» (ETP=bis(2-(diphenylphosphino)ethyl)phenylphosphine) has been shown to contain the binuclear cation [Ru 2 (μ-Cl) 3 (ETP) 2 ] + and Cl - -. In CDCl 3 the cation is present as a mixture of the staggered and eclipsed isomeric forms. The X-ray crystal structure of [Ru 2 (μ-Cl) 3 (ETP) 2 ] (CF 3 SO 3 ) shows that only the eclipsed form is present in the single crystals grown from CH 2 Cl 2 /CHCl 3 /PhMe