R. S. Silva, E. Tfouni
Jul 1, 1992
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0
Influential Citations
27
Citations
Journal
Inorganic Chemistry
Abstract
Reported are the syntheses and some properties of the ruthenium(II) macrocyclic complexes, trans-[Ru II Cl(cyclam)L] (cyclam=1,4,8,11-tetraazacyclotetradecane; L=4-picoline (4-pic), pyridine (py), isonicotinamide (isn) or 4-acetyl-pyridine (4-acpy)). The syntheses of these complexes were performed by reducing trans-[RuCl 2 (cyclam)] + to the Ru(II) form, which undergoes the labilization of only one chloride, and addition of excess L.