N. Bailey, D. Fenton, M. L. Gonzalez
Sep 15, 1984
Citations
0
Influential Citations
11
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract Complexes of bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)iron(II) with bidentate-N-containing ligands (1,2-diaminoethane; N,N-dimethyl-1,2-di-aminoethane; N,N′-dimethyl-1,2-diaminoetane; 1,10-phenanthroline; 2,2′-bipyridyl), the 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato anion, tri- and tetradentate N-containing ligands (N-2-dimethyl-aminoethyl-N,N′,N′-trimethyl-1,2-diaminiethane; N,N′-bis(2-methylaminoethyl-N,N′-dimethyl)-1,2-diaminoethane), tetradentate macrocyclic ligands (5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetra-deca-4,11-diene; 5,12-dimethyl-7,14-diphenyl-1,4,8 11-tetraazacyclotetradecane; 5,7,7,12,14,14-hexamethyl-1,4,8-11-tetraazacyclotetra-decane) and tetradentate metal Schiff base complexes (based on salen and acen) have been prepared and their spectral and chemical properties investigated. The crystal structure of [Cu(hfpd)2/2 (trien-Me6) is monoclinic, space group P21/a; two [Cu(hfpd)2] units are bridged by the (trien-Me6) ligand and the whole binuclear molecule possesses crystallographically imposed inversions symmetry.