Yin-Hua He, Y. Lan, Cai‐Hong Zhan
Apr 20, 2009
Citations
0
Influential Citations
26
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract Employing an unsymmetrical 6-hydroxynicotinic acid as a bridging ligand, we have prepared a new NLO-active two-dimensional cadmium coordination polymer [Cd 8 (nicO) 8 (phen) 8 · (H 2 O)] n ( 1 ) (H 2 nicO = 6-hydroxynicotinic acid, phen = 1,10-phenanthroline) under hydrothermal condition. At room temperature, 1 shows strong fluorescent emission bands in the solid state and a SHG efficiency of about 8 times that of KDP (KH 2 PO 4 ). On the basis of TG/DTA analyses, the structure is thermally stable up to 370 °C.