Deiaa M. Harraz, Jeffery T. Davis
Feb 8, 2018
Citations
0
Influential Citations
10
Citations
Journal
Chemical communications
Abstract
Guanosine 5'-monophosphate (5'-GMP) and Fe(iii)-heme form a supramolecular catalyst with peroxidase activity. Catalysis, which depends on self-assembly of 5'-GMP into a G-quadruplex that binds hemin, can be modulated by nucleotide concentration, temperature and the identity of the nucleotide's sugar.