An-Kai Wu, Kwang‐Ming Lee
Apr 24, 2012
Citations
0
Influential Citations
7
Citations
Journal
CrystEngComm
Abstract
A series of 1-(2-amino-2-oxoethyl)-3-carbamoylpyridin-1-ium salts with different anions (Cl−, Br−, BF4−, NO3−, OTf−, PF6− and BPh4−) have been synthesized and characterized by single crystal X-ray diffraction. The results demonstrate that the L-shaped diamide pyridinium cations can aggregate convergently to form a tubular structure or divergently to form a one-dimensional ribbon structure or two-dimensional brick, grid and sheet structures via different hydrogen bonding catemer motifs, including conventional N–H⋯O type (BPh4− (7)), the nonconventional N–H⋯O types (Cl− (1)) and, the mixed N–H⋯O/C–H⋯O type (OTf (5) and PF6− (6)), and the interesting pure C–H⋯O types (Cl− (1), Br− (2) and BF4− (3)).