J. Lellouche, S. Koeller
Jan 12, 2001
Citations
0
Influential Citations
39
Citations
Journal
The Journal of organic chemistry
Abstract
The two electrophilic Vilsmeier-Haack reagents POCl3.DMF 2 or (CF3SO2)2O.DMF 3 mediate the one-step and selective conversion of O-triethylsilyl (O-TES), O-tert-butyldimethylsilyl (O-TBDMS), O-tert-butyldiphenylsilyl (O-TBDPS), and O-triisopropylsilyl (O-TIPS) ethers of D-glucal to the corresponding C(6)-O-formates.