Jiří Trejbal, M. Petrisko, J. Pašek
Nov 1, 2007
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0
Influential Citations
3
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Journal
Chemical Engineering & Technology
Abstract
A research investigation into the synthesis of 1, 4-diazabicyclo[2.2.2]octane from ethylendiamine over zeolite ZSM-5 was carried out. A number of side products such as alkylpyrazines, alkylpiperazines and alkyl-1, 4-diazabicyclo[2.2.2.]octanes were identified in the reaction mixture. A chemical mechanism based on elimination, condensation, cracking and proton transfer reactions was proposed for the formation of these compounds.