H. Makomo, S. Masson*, Didier Putman
May 1, 1996
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Influential Citations
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Journal
Phosphorus Sulfur and Silicon and The Related Elements
Abstract
Abstract The diisopropyl (allylthiomethyl)phosphonates (variously substituted on the allylic group) are submitted to the [2,3]-sigmatropic rearrangement, via either the carbanions or the sulfonium ylides. Synthetic potentialities are examined, and in particular new (1-mercaptobut-3-enyl)phosphonates are conveniently prepared.