K. Andrianov, L. M. Volkova, N. V. Delazari
1967
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Journal
Chemistry of Heterocyclic Compounds
Abstract
Reaction of 1,3-bis(methyldichlorosilyl)propane with alcohols gives (methylalkoxychlorosilyl)propanes. Hydrolysis of the latter with the calculated amount of water in the presence of a HCl acceptor gives 2, 6-dimethyl-2,6-dialkoxy-1-oxa-2,6-disilacyclohexanes. Hydrolysis of 1,3-bis(methyl-dichlorosilyl)propane and 1,3-bis(methylalkoxy-chlorosilyl)propane gives a tricyclic carbocyclosiloxane. A study is made of the reactions of 2, 6-dimethyl-2, 6-dialkoxy-1-oxa-2, 6-disilacyclohexane with alcohols, triethylsilanol, triethylchlorosilane, and C6H5MgBr.