M. Alonso, J. A. Casares, P. Espinet
Aug 13, 2001
Citations
0
Influential Citations
9
Citations
Journal
Tetrahedron Letters
Abstract
Abstract The complexes [Rh(diene)(L-L′)](BF 4 ), and [RhCl(CO)(L-L′)] (diene=COD 1,5-cyclooctadiene; L-L′=P(bzN)Ph 2 , P(bzN) 2 Ph, P(bzN) 3 , PePy, or PePy 2 , bzN=2-(dimethylaminomethyl)phenyl, PePy n =P(CH 2 CH 2 Py) n Ph 3− n ; Py=2-pyridyl; n =1,2) are poor catalysts for the hydrosilylation of 1-hexyne, but excellent catalysts for the silylformylation of 1-hexyne in tetrahydrofurane at atmospheric pressure and room temperature.