E. B. Brouwer, G. Enright, J. Ripmeester
Jun 11, 1997
Citations
0
Influential Citations
50
Citations
Journal
Journal of the American Chemical Society
Abstract
The majority of p-tert-butylcalix[4]arene inclusion compounds are 4-fold symmetric in the solid state, with the guest molecular and the host symmetry axes approximately aligned. In contrast, nitrobenzene (and related guests) induces a permanent symmetry-reducing distortion of the p-tert-butylcalix[4]arene compound and occupies a position in which the guest molecular axis is no longer aligned with that of the host. These compounds have been characterized by single-crystal X-ray diffraction as well as 13C CP-MAS and 2H NMR in the solid state. Introduction of propane as a second, minority guest in sufficient quantities induces the alignment of the nitrobenzene molecular axis with the host C4 symmetry axis. Nitrobenzene-d5 guest dynamics in the symmetric and asymmetric structures reveal a much stronger host·guest interaction in the latter. The nature of the asymmetry is due to a cooperative effect rather than any intrinsic property of the individual p-tert-butylcalix[4]arene·guest units. In general, this work...