George C. Fortman, S. Nolan
Oct 1, 2010
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Influential Citations
23
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Journal
Organometallics
Abstract
The relative L−Au bond dissociation enthalpies of [Au(L)Cl] (L = tetrahydrothiophene (tht), PCynPh(3−n), [1,1′-biphenyl]-2-yldicyclohexylphosphine (Cy-JohnPhos), dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphine (SPhos), dicyclohexyl[2′,4′,6′-tris(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine (XPhos), P(OPh)3, P(O-2,4-tBu2Ph)3, P(OiPr)3, and the two enantiomers of 1,1′,1′′-[phosphinidynetris[oxy-(1-S/R)-[1,1′-binaphthalene]-2′,2-diyl]] tricyclo[3.3.1.13,7]decane-1-carboxylic acid ester) are examined. These enthalpic values are examined in terms of the intrinsic steric and electronic properties of the ancillary ligand. Estimates of the absolute BDE for the investigated ligands are presented.