D. Chapon, Chris J. Husson, P. Delangle
Jul 12, 2001
Citations
0
Influential Citations
20
Citations
Journal
Journal of Alloys and Compounds
Abstract
Abstract The aqueous complexation reactions of trivalent lanthanide cations with the ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (TACI) have been characterised using potentiometry, electrospray ionisation mass spectrometry and solution NMR. Isostructural trinuclear complexes, [Ln3(TACIH−3)2]3+, are formed all along the series and their stability constants are extremely dependent on the cation radius.