A. Hoz, A. Sánchez-Migallón, Beatriz Pelado
Nov 6, 2013
Citations
0
Influential Citations
4
Citations
Journal
Arkivoc
Abstract
An efficient and green synthesis of 2,4-dimethoxybenzyaminotriazines is described, by reaction of disubstituted triazines with 2,4-dimethoxybenzylamine under microwave irradiation and in solvent-free conditions. NMR spectroscopy has been used to determine the free energy of activation of the restricted rotation of the ArylN-triazine bond that is a slow process at room temperature. Contrarily, the benzylN-triazine bond shows a rapid rotation at room temperature.