Lee Ikchoon, Huh Chul, Lee Hai Whang
1989
Citations
0
Influential Citations
1
Citations
Journal
Bulletin of The Korean Chemical Society
Abstract
The methanolysis reactions of phenylacetyl chlorides have been investigated in methanol-acetonitrile mixtures at temperatures ranging - Substituent and solvent effects on the rate supported an associative mechanism for the solvolysis. Activation parameters indicated that the reaction is entropy controlled, while the a/s ratios of the Taft's solvactochromic correlation proved to be remarkably constant with a typical value of 0.50 that is consistent for the reactions proceeding by a typical path.