Maritza J Flores, Brandon Mai, J. Tanski
Aug 23, 2023
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Journal
Acta Crystallographica Section E: Crystallographic Communications
Abstract
9-Methoxy-3,4,5,6-tetrahydro-1H-benzo[b]azonine-2,7-dione and 6-methoxy-1,2,3,4-tetrahydrocarbazole represent the structures of a benzoazonine that contains a nine-membered ring and its parent tetrahydrocarbazole. The molecules of the former pack together via strong amide N—H⋯O hydrogen bonding and weak C—H⋯O interactions, whereas the parent tetrahydrocarbazole packs with C/N—H⋯π interactions, as visualized by Hirshfeld surface characterization.