D. Doskočilová, J. Pecka, J. Dybal
Aug 1, 1994
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Journal
Macromolecular Chemistry and Physics
Abstract
The product of 1-decene oligomerization with AlCl 3 as catalyst was fractionated by vacuum distillation, with the highest fraction consisting predominantly of the hexamer. The structure of the fractions was characterized by 1 H and 13 C NMR and Raman spectroscopy. The oligomers contain predominantly long branches (7 carbons and longer) and always one double bond per molecule, with strong predominance of tri- and tetra-substituted types. The minority structures are analyzed, and the polymerization and isomerization mechanisms are discussed