E. Taskinen, Nina Lindholm
May 1, 1994
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0
Influential Citations
15
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Journal
Journal of Physical Organic Chemistry
Abstract
The relative thermodynamic stabilities of 2-propenylbenzene (allylbenzene), and the E and Z forms of 1-propenylbenzene were determined over the temperature range 50–170°C by chemical equilibration in DMSO solution with t-BuOK as catalyst. The values of the thermodynamic parameters ΔG⊖, ΔH⊖ and ΔS⊖ at 298·15 K for each isomerization reaction between the title compounds were evaluated.