Toshiyuki Nakamura, T. Makino, T. Sugahara
2003
Citations
3
Influential Citations
194
Citations
Quality indicators
Journal
Chemical Engineering Science
Abstract
The four-phase coexistence curves for the structure-H hydrates of methylcyclohexane and cis-1,2-dimethylcyclohexane in the presence of methane are measured in the temperature range 274.09–288.29K and pressure range 1.42–8.89MPa. Very large pressure reductions from the pure methane hydrate are observed by forming structure-H hydrates. The present investigation on the trans-1,2-dimethylcyclohexane system reveals that the limit of the largest-cage occupancy for the structure-H hydrate is laid between the 1,2-dimethylcyclohexane stereo-isomers.