P. Beckmann, L. Happersett, A. V. Herzog
Jul 15, 1991
Citations
0
Influential Citations
23
Citations
Journal
Journal of Chemical Physics
Abstract
We have investigated the dynamics of the ethyl groups and their constituent methyl groups in polycrystalline ethylbenzene (EB), 1,2‐diethylbenzene (1,2‐DEB), 1,3‐DEB, and 1,4‐DEB using the solid state proton spin relaxation (SSPSR) technique. The temperature and Larmor frequency dependence of the Zeeman spin‐lattice relaxation rate is reported and interpreted in terms of the molecular dynamics. We determine that only the methyl groups are reorienting on the nuclear magnetic resonance time scale. The observed barrier of about 12 kJ/mol for methyl group reorientation in the solid samples of EB, 1,2‐DEB, and 1,3‐DEB is consistent with that of the isolated molecule, implying that in the solid state, intermolecular electrostatic interactions play a minor role in determining the barrier. The lower barrier of 9.3±0.2 kJ/mol for the more symmetric 1,4‐DEB suggests that the crystal structure is such that the minimum in the anisotropic part of the intramolecular potential is raised by the intermolecular interaction...