M. Satoh, N. Miyaura, A. Suzuki
Aug 5, 1986
Citations
0
Influential Citations
33
Citations
Journal
Chemistry Letters
Abstract
The reaction of diisopropyl (Z)-(1-bromo-1-alkenyl)boronates readily obtainable, with organolithiums and bases takes place readily to give (E)-(1-organo-1-alkenyl)boronates, the cross-coupling of which with various organic halides proceeds smoothly in the presence of Pd-catalyst and base to afford stereodefined trisubstituted alkenes in good yields.