Frank K. Cartledge, Joanne M. Wolcott, Jacques Dubac
1978
Citations
0
Influential Citations
25
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Preparations, separations of geometric isomers, and structural assignments based on nmr and on chemical evidence are described for a number of 1-substituted 1,2-dimethylsilacyclopentanes. A number of stereospecific reactions have been observed, and the stereochemistry is in all cases the same as that observed for acyclic silanes. A discussion of the role of ring strain in determining stereochemical outcome and reaction rates is presented.