B. Shainyan, V. Meshcheryakov, A. Albanov
Sep 12, 2005
Citations
0
Influential Citations
11
Citations
Journal
Tetrahedron Letters
Abstract
Abstract Dynamic NMR of 1,3,5-tris(trifluoromethylsulfonyl)-1,3,5-triazinane reveals two dynamic processes: ring inversion leading to equilibrium between two degenerate rotamers of C s symmetry (Δ G ≠ = 13.5 kcal/mol), and rotation about the S–N bond leading to equilibrium between the C s (more stable) and C 3 v (2.12 kcal/mol less stable) rotamers (Δ G ≠ = 13.0 kcal/mol).