Ivan G. Georgiev, Dejan-Krešimir Bučar, L. MacGillivray
Jun 29, 2010
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0
Influential Citations
38
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Journal
Chemical communications
Abstract
Reaction of 4-vinylpyridine with AgClO(3) yields a crystalline solid that supports a stereospecific and quantitative [2+2] photodimerisation of two terminal olefins. Structural dynamics of the -CH[double bond, length as m-dash]CH(2) group, nature of the counterion, and extended packing influence the photoreactivity.