W. Roth, W. Pigman, I. Danishefsky
1964
Citations
0
Influential Citations
7
Citations
Journal
Tetrahedron
Abstract
Catalytic reduction of d-fructose oxime yielded 2-amino-2-deoxy-d-mannitol which was isolated as the crystalline peracetylated derivative. This was converted to 2-acetamido-2-deoxy-d-mannitol. The mono- and di-O-isopropylidene derivatives of this material were prepared. Oxidaiton of the latter, followed by hydrolysis yielded small amounts of a product having the same Rf as 2-acetamido-2-deoxy-d-mannose.