L. Barclay, P. Khazanie, K. Adams
Sep 15, 1977
Citations
0
Influential Citations
4
Citations
Journal
Canadian Journal of Chemistry
Abstract
tert-butylphenyl)-~ert-butyl-a-2-(5-tert-butypyridyl)nitrone, and diethyl N-(2,5-di-tert-butylphenyl)phosphoramidate. In contrast deoxygenation of 2,4,6-tri-tert-butylnitrosobenzene (2) yielded mainly 3,3-dimethyl-5,7-di-tert-butyl-2,3-dihydrondoe (80%), together with small amounts of 2,4,6-tri-tert-butylaniline and a product of side chain rearrangement, 2-(2-methyl-3propeny1)-4,6-di-tert-butylaniline. Reaction pathways involving nitrenoid intermediates account for the various products. The different types of products from 1 and 2 are explained in terms of differential steric and conformational effects.