J. R. Bowser, L. R. Nevinger, S. Krüger
Sep 20, 1988
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Journal
Synthesis and Reactivity in Inorganic and Metal-organic Chemistry
Abstract
Abstract Reactions of tert-butyl (chloro) diphenylsilane with ammonia, primary and secondary amines, or their lithium salts produce compounds having the general formula t-Bu(C6H5)2SiNRR'. These compounds are viscous, high-boiling liquids with high thermal stabilities and unusually low reactivities toward hydrolysis. Comparisons are made to the tert-butyldimethylsilyl analogues.