M. Iwasaki, S. Nagase, R. Kojima
Mar 1, 1957
Citations
0
Influential Citations
13
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The molecular structure of 1,2-difluorotetrachloroethane was studied by the electron diffraction method. The existence of the two isomeric forms, trans and gauche, was ascertained and the amount of the gauche form was found to be 55±10 per cent. This corresponds to the energy difference of 0−500 cal./mol. the trans form being more stable. The interatomic distances and the valency angles were determind as follows: C—F=1.38±0.02 A, C—Cl=1.76±0.01 A, C—C=1.54±0.06 A,