Kang Wanli
2007
Citations
0
Influential Citations
1
Citations
Journal
Journal of Northeast Normal University
Abstract
The complex di-n-butyltin di-2-(2-methoxy-4-formylphenoxy)acetic ester(1) was synthesized by the reactions of di-n-butyl tin oxide with 2-(2-methoxy-4-formylphenoxy)acetic acid and azeotropic removal of water with benzene.The compound(1) was characterized by elemental analysis,1H NMR,FT-IR spectroscopy and single crystal X-ray diffraction analysis.The crystal belongs to space group Pī,the cell parameter are:a=1.403 92(12) nm,b=1.694 09(15) nm,c=2.000 93(18) nm,α=112.527 0(10)°,β=96.879(2)°,γ=100.041(2)°,Z=2.The Sn atoms are considered as five-coordinate and exist as distorted trigonal bipyramidal geometry in a one-dimensional chain.The compound(1) exhibit good antibacterial properties,while the antibacterial properties decrease in the order the compound(1) di-n-butyltin oxide2-(2-methoxy-4-formylphenoxy)acetic acid.