I. Gautier-Luneau, A. Mosset
Apr 1, 1988
Citations
0
Influential Citations
10
Citations
Journal
Journal of Solid State Chemistry
Abstract
Abstract The crystal structure of the title compound has been determined by X-ray diffraction methods. It crystallizes in the tetragonal system, space group I4 1 a with refined lattice parameters: a = 9.901(3) A, b = 27.362(8) A, and Z = 16. The structure consists of a tridimensional network of interconnected Ba4 (CH3COO)8 units. The four Ba atoms are linked by four μ2-O and four μ3-O. These formal associations Ba4L8 are associated in the three directions by double μ2-O bridges. The barium surrounding is a very distorted monocapped square antiprism. The two independent acetate groups show different bonding schemes.