P. Zugenmaier
Apr 22, 2013
Citations
0
Influential Citations
0
Citations
Journal
Molecular Crystals and Liquid Crystals
Abstract
Bibenzyl-4-yl-[5,6-dihydro-6-oxo-1-(4-pentenyl)pyridine-3-carboxylate]-4′-yl-(6- methoxypyridine-3-carboxylate) (Z-EFH) crystallizes in a triclinic space group of P-1 with a = 6.118(2) Å, b = 15.821(6) Å, c = 16.910(6) Å, α = 116.65(2)°, ß = 96.31(2)°, γ = 92.55(2)°, V = 1445.9(9) Å3 at ambient temperature. The compound was obtained by synthesis of a targeted compound with a pentenyloxy derivatized pyridine ring at one end of the molecule which was rearranged during synthesis by transferring the pentenyl group to the nitrogen of the pyridine ring and thus creating a derivative of a newly formed 2-pyridone ring. The packing arrangement is dominated by strong dipolar carbonyl–carbonyl interaction.