R. Bardi, A. Piazzesi, L. Sindellari
1981
Citations
0
Influential Citations
10
Citations
Journal
Inorganica Chimica Acta
Abstract
The structure of cis -dichlorobis(N,N-dimethyl-O-ethylthiocarbamate)platinum(II) has been determined from three-dimensional X-ray data. The complex crystallizes in the orthorhombic system, space group P bca , with molecules in a unit cell of dimensions a = 14.681(5), b = 17.136(6), c = 14.357(5) A . A full-matrix least-squares refinement has led to a value of the conventional R index (on F) of 0.044 for the 1501 observed reflections with I ⩾ 3σ(I). The complex is a typical square-planar Pt(II) species. Structural parameters: PtCl 2.320(4) and 2.321(4); PtS 2.285(4) and 2.291(4) A ; Cl(1)PtCl(10) 90.5(2), S(1)PtS(10) 87.1(2), Cl(1)PtS(1) 91.1(2) and Cl(10)PtS(10) 91.8(2)°.